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Abstracts from Recent Issues: Vol. 35, No. 1, February 2009

Vol. 35, No. 1, February 2009

Compatability of Cereal Straw with Hydration of Cement

Compatability and Attenuative Properties of Blast Furnace Slag Treated Laterite

Application of Ionizing Radiation for Sludge Disinfection and Its Use for Irrigation and Fertilization

Sorption Potential of the Biomasses of Peanut Hull and Fly Ash for Decolorization of Methylene Blue Aqueous Solution

An Improved Numerical Design Method for the Remediation of Contaminated Sites Based on Sensitive Tracer Tests

Driving Commercial and Industrial Waste Reduction in Queensland, Australia — The Potential Application of a UK Waste Minimisation Club Model
 

COMPATIBILITY OF CEREAL STRAW WITH HYDRATION OF CEMENT

P. Soroushian
Department Civil and Environmental Engineering, Michigan State University
Room 3546, Engineering Building, East Lansing, MI 48824-1226, USA
Email: soroushi@egr.msu.edu; Tel: (517) 355 2216; Fax: (517) 432 1827

O. Simsek
Department of Construction, Faculty of Technical Education
Gazi University, 06500, Ankara, Turkey
Email: simsek@gazi.edu.tr

M. Elzafraney
Technova Corporation
1926 Tunrner St., Lansing, MI 48906, USA
Email: tchnv@aol.com

T. Ghebrab
Department Civil and Environmental Engineering, Michigan State University
Room 3546, Engineering Building, East Lansing, MI 48824-1226, USA
Email: ghebrabt@msu.edu

ABSTRACT

 

Cereal straw is an abundantly available agricultural by-product with attractive mechanical performance and cost position for reinforcement of cement-based products. The composition of straw, however, is distinguished from that of wood by the presence of relatively large quantity extractives with potentially strong inhibitory effects on strength development of cement. Thin-sheet fiber cement products offer attractive technical, economic and aesthetic qualities for use in diverse building construction applications, including siding and tile backerboard. Commercially successful thin-sheet fiber cement products generally utilize chemically processed wood pulp or mechanically milled wood as reinforcement for achieving enhanced levels of flexural strength, toughness and workability. Cereal straw offers a slender geometry which favors their mechanical processing as replacement for milled wood in thin-sheet cement products. As a renewable resource and as a generally low-valued agricultural residue, straw offers economic and environmental advantages for replacement of wood in thin-sheet cement products. The differences in composition of wood and straw should be considered in devising pre-treatment techniques for use of straw in conjunction with cement. Such pre-treatments should address the potential for inhibitory effects of some straw constituents on strength development of cement.

Keywords: Straw; Treatment; Cement; Strength development; Reinforcement

COMPATIBILITY AND ATTENUATIVE PROPERTIES OF BLAST FURNACE SLAG TREATED LATERITE

Kolawole J. Osinubi
Professor, Dept. of Civil Engineering, Ahmadu Bello University
Zaria 810001 NIGERIA
Tel: +2348037037241, Email: kosinubi@yahoo.com

Adrian O. Eberemu
Lecturer, Dept. of Civil Engineering, UNIAGRIC Makurdi
Benue State, NIGERIA
Email: aeberemu@yahoo.com

ABSTRACT

 

Major concerns exist regarding potential pollution problems related to contamination by toxic liquids emanating from waste landfills. Increasing environmental awareness is making it necessary to assess the effects of waste leachates in proposed clayey liners for waste landfills. Results of a study on the feasibility of using laterite treated with ground blast furnace slag (BFS) as a construction material for waste containment liners and impermeable covers are presented. Liners can be constructed using laterite treated with ground BFS to meet the regulatory permeability value of < 1x 10-9 m/s. The effects of permeation with municipal solid waste (MSW) leachate on compacted soil treated with up to 15% ground BFS at the energy of the British Standard heavy (BSH) compaction using different molding water contents for a period of one month are reported. Batch equilibrium studies were conducted for a duration of 48 hours using 0, 5, 10, 15 and 100% ground BFS treated soil, respectively. The MSW leachate had no detrimental effect on the liner permeability. Adsorption isotherms were obtained for the cations of calcium, iron and chromium that were selected to represent the dominant and critical contaminants in the leachate and these showed strong attenuative properties. 5% BFS treatment gave the optimum mix performance.

Keywords: Adsorption Isotherm, Attenuation, Batch Equilibrium, Compatibility, Hydraulic Conductivity, Laterite, Municipal Waste Leachate

APPLICATION OF IONIZING RADIATION FOR SLUDGE DISINFECTION AND ITS USE FOR IRRIGATION AND FERTILIZATION

G. Shani
Department of Biomedical Engineering, Ben Gurion University
POB 653 Beer Sheva, ISRAEL
Email: gshani@bgu.ac.il

S. Segman-Magidovich
Department of Biothechnology, Ben Gurion University
POB 653 Beer Sheva 84105, ISRAEL

ABSTRACT

 

The sludge produced in the central, most populated area in Israel, is now dumped into the sea. Ionizing radiation was used to investigate the possibility of developing an industrial method for disinfection of the sludge, preparing it for use in farm land for irrigation and fertilization. A simple and inexpensive method for disinfection and preparing it for agricultural use is proposed. Sludge samples were irradiated with photons and electrons, it was found that relatively low radiation dose is enough to bring it to level A which is acceptable for the proposed use. Any dose of gamma radiation from a Co 60 source, from 0.2 Mrad and up, killed all coliforms in the sludge. Similar results were obtained for 3 MeV electrons. The irradiation stopped all biological activity in the sludge, therefore causing the solid part to separate from the water and sink. This stopped the gas (odor) emission from the sludge. The radiation did not have any effect on the heavy metals concentration in the sludge, but had some effect on the concentration of some of the light elements (some of it remained in the solid). The water, containing important minerals, was then tested for field irrigation. The product was tested for irrigation using droppers and found to be suitable.

Keywords: Sludge, Irradiation, Coliform, Disinfection, Gases emission, Droppers

SORPTION POTENTIAL OF THE BIOMASSES OF PEANUT HULL AND FLY ASH FOR DECOLOURIZATION OF METHYLENE BLUE AQUEOUS SOLUTION

G.M. Taha
Chemistry Department, Aswan Faculty of Science
Aswan 81528, EGYPT
Email: gmtaha@hotmail.com

ABSTRACT

 

The sorption potential of either peanut hull or fly ash to decolourize the aqueous solution of methylene blue (MB) was investigated at room temperature. Many operating variables were studied in a batch technique. Of these, solution pH, dosage of the used sorbent biomass, initial dye concentration and the applied contact time.
The resulting data was fitted and was more suitable by Langmuir isotherm model than the Freundlich one confirming the formation of monolayer from the sorbed dye on the sorbent surface. All parameters of Freundlich and Langmuir were calculated from the experimental results. The transient behaviour of the batch sorption process at different initial MB concentration was analyzed utilizing Lagergren pseudo first-order kinetic model and Ho and McKay pseudo second-order model.

Keywords: Sorption, Peanut Hull, Fly Ash, Methylene Blue, Isotherm Models, Kinetic Models, Chemisorption

AN IMPROVED NUMERICAL DESIGN METHOD FOR THE REMEDIATION OF CONTAMINATED SITES BASED ON SENSITIVE TRACER TESTS

Kazuei Ishii and Toru Furuichi
Laboratory of Sound Material-Cycle Systems Planning
Graduate School of Engineering, Hokkaido University
N13, W8, Kita-ku, Sapporo, 060-8628, JAPAN
Tel: +81-011-706-7284; Fax: +81-011-706-7287
Email: k-ishii@eng.hokudai.ac.jp

ABSTRACT

 

We proposed an improved numerical design method for the remediation of contaminated sites based on a sensitive tracer test using rare earth metals such as holmium. The numerical design method was then applied to a real contaminated site, where immediate countermeasures were required because of detection of high arsenic concentration in a spring near a sea line outside the site. First, the sensitive tracer test using insium, europium and holmium under natural gradient condition revealed the groundwater flow path from the three suspected source points to the sea line, and analysis of the breakthrough curve for each tracer compounds determined the parameters, such as the hydraulic conductivity and dispersivity. A site-specific model representing the distribution of acrcenic concentration in groundwater identified the source points, responsible for the contamination of the spring, and revealed that contaminated groundwater might flow out of the site boundary. A vertical wall was designed to prevent contaminants spreading from the site, and the change in the arsenic concentration after the construction of the vertical wall was predicted. The prediction had similar tendency to the actual decrease in arsenic concentration over a two-year monitoring phase. Consequently, our numerical design based on the sensitive tracer test predicted that the contamination level in the groundwater around the spring would continuously decrease toward remediation.

Keywords: Groundwater contamination, sludge contaminated by arsenic, numerical design method, sensitive tracer test

DRIVING COMMERCIAL AND INDUSTRIAL WASTE REDUCTION IN QUEENSLAND, AUSTRALIA — THE POTENTIAL APPLICATION OF A UK WASTE MINIMISATION CLUB MODEL

Georgina Davis
Griffith University, Centre for Environmental Systems Research
Brisbane QLD 4115, AUSTRALIA

Paul Phillips and Thomas Coskeran
University of Northampton, SITA Centre, School of Applied Sciences
Northampton NN2 7AL, UK

ABSTRACT

 

Queensland (QLD) is the second largest state in Australia with an area of 1,734,157 km2 and a population of some 4,132,000 (less than 20% of Australia’s total population). The majority of QLD’s population is located in the South East (SEQ) region around Brisbane and the Gold Coast with further population densities along the coast. SEQ is growing rapidly, with SEQ receiving over 1,000 new immigrants (both interstate and international) to the region every week, which is stimulating the housing, retail and commercial and industrial sectors. This growth in population and development is leading to an increase in waste arisings across all sectors. During 2005, QLD generated approximately 444,000 tonnes of commercial and industrial waste, with only 23,000 tonnes being recycled, equating to only 5% of the amount generated. By comparison, during 2005 the UK generated 83 million tonnes of commercial and industrial wastes of which approximately 45% was recycled. QLD has a suite of environmental and specific waste management legislation relating to the management of all waste streams which adopts the waste management hierarchy. The regulatory framework of any State or Country can if well designed drive sustainable waste management practices within the commercial and industrial sectors.
Waste minimisation clubs (WMCs) were initiated in the 1990s in the UK in order to assist commercial organisations minimise their waste streams and identify re-use and recycling opportunities, including e.g. waste exchanges. WMCs have been an important demonstration opportunity for companies to grasp the benefits of the sustainable management of commercial and industrial wastes as well as the possible adoption of cleaner production through new technology.
This paper reviews the trend of WMCs in the UK and discusses their potential application to QLD. It explores the drivers and barriers for such implementations within QLD, including the absence of a landfill levy and legislative barriers. The paper also discusses Australian government initiatives for improving resource efficiency within industry, and the benefits and limitations of these schemes. Case studies from the UK are then provided to ascertain the opportunities for possible WMC development in QLD.

Keywords: Resource, Waste Minimisation Clubs, Landfill Levy, Queensland, UK

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